
In an article published in the prestigious scientific journal Science Advances, the research group shows the phenomenon in action in three specially built molecules, and proposes a model for how it works.
“I originally had the idea many years ago, and then I just happened to meet Professor David González-Rodríguez, from the Universidad Autónoma de Madrid, who had constructed a molecule of exactly the type we were looking for,” says Martijn Kemerink.
Ferroelectricity

The molecules designed according to the model developed by the LiU researchers tend to spontaneously place themselves on top of each other to form a stack or a supramolecular wire, with a diameter of just a few nanometres. These wires can subsequently be placed into a matrix in which each junction constitutes one bit of information. This will make it possible in the future to construct extremely small digital memories with very high information density. The synthesis of the new molecules is, however, still too complicated for practical use.
Building molecules
“We have developed a model for how the phenomenon arises in principle, and we have shown experimentally that it works for three different molecules. We now need to continue work to build molecules that can be used in practical applications,” says Professor Martijn Kemerink, from Complex Materials and Devices at Linköping University, and principal author of the article.The article: Ferroelectric self-assembled molecular materials showing both rectifying and switchable conductivity, Andrey V. Gorbunov, Miguel Garcia Iglesias, Julia Guilleme, Tim D. Cornelissen, W. S. Christian Roelofs, Tomas Torres, David González-Rodríguez,
E. W. Meijer and Martijn Kemerink. Science Advances 2017
DOI 10.1126/sciadv.1701017
