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Henrik Pedersen

Professor

I teach inorganic chemistry and head a research group focusing on various aspects of CVD, chemical vapour deposition, a chemical method for deposition of thin layers of materials.

Presentation

Research

Chemical Vapour Deposition is a fundamental process for making coatings and thin layers of materials. It is used in the manufacturing of electronics, cutting tools and photochromic windows. My research is about understanding and developing CVD: which chemical reactions happens during CVD of a certain material, and how can these be controlled to make better CVD processes and better materials? The aim is to facilitate new and better electronics by developing CVD for lower temperatures and higher precision.

I received my M.Sc. in Chemistry 2004, my Ph.D. in Materials Science 2008, both from Linköping University. After a stint as industrial researcher at Sandvik Tooling Research and Development center in Stockholm, Sweden 2009-2010, I returned to academia and is today Professor of Inorganic Chemistry. I have been also been visiting professor at Carleton University in Ottawa, Canada 2016.

My research is done at the interface between chemistry, physics, materials science, and electronics. My research group therefore consists of synthetic chemists, physical chemists, quantum chemists, materials scientists, and semiconductor physicists.

Henrik Pedersen

In one of our ongoing projects, we study how time-resolved CVD can be used to improve the material quality, and thereby the performance, of the group 13 nitrides AlN, GaN, InN, and their alloys. Here we use the most well-known time-resolved CVD method; atomic layer deposition (ALD) with time-resolved supply of precursor molecules and energy in the form of plasma discharges. An important part of the project is to develop new precursor molecules for the group 13 metals. This is done in close collaboration with Professor Seán Barry vid Carleton University i Ottawa, Canada. Another important part is to study how molecules react at the surface during the ALD process, it is mainly done by quantum chemical computations in close collaboration with Professor Lars Ojamäe at Linköping University.

Thermal ALD

In another project we develop a new CVD method where the free electrons in a plasma discharge are used to reduce the metal centers in chemisorbed precursors to a metallic film. This research is done in close collaboration with Professor Daniel Lundin at Linköping University. The aim of this research is to develop new methods for metal deposition and an understanding of how plasma electrons can be used for surface chemistry.

In our research on CVD of boronbased materials we work with boron carbide for neutron detectors. Since neutrons are electrically neutral, they are very hard to detect. A nuclear reaction is needed where neutrons react with certain isotopes such as 10B or 157Gd. In collaboration with Professor Jens Birch at Linköping University and the European Spallation Source (ESS) in Lund, Sweden, we study thin films with high concentration of 10B that will be the basis of several neutron detectors at ESS. We also study CVD of boron nitride as a possible future electronic material in collaboration with Docent Hans Högberg at Linköping University.

Feels free to contact me if You are interested in a research collaboration.

Teaching

I teach basic- and advanced level chemistry. You will meet me at the introductory courses on General-, Inorganic-, and Environmental Chemistry at the Chemistry-, Analytical Chemistry Technology-, and Chemical Biology Bachelor’s programmes, and in Materials Chemistry at the Master’s programme in Chemistry. My fundamental teaching philosophy is that “learning chemistry is to learn how to think chemistry”. I constantly try to point to how almost everything in Chemistry can be related back to fundamental concepts like electronegativity and atomic- and molecular orbitals. I also try to point out how much understanding you can get on a molecule by looking at its structure.

Video


Podcast on Green CVD

Green CVD: How Sustainable is Thin Film Deposition? 

In this podcast Henrik Pedersen, Sean Barry, and Jonas Sundqvist talk about their publication in JVSTA about Green CVD. They discuss a new research field, more sustainable thin film deposition practices and more.

Organisation

Research

Publications

2024

Arun Haridas Choolakkal, Pentti Niiranen, Samira Dorri, Jens Birch, Henrik Pedersen (2024) Competitive co-diffusion as a route to enhanced step coverage in chemical vapor deposition Nature Communications, Vol. 15 (Article in journal) Continue to DOI
Pamburayi Mpofu, Houyem Hafdi, Jonas Lauridsen, Oscar Alm, Tommy Larsson, Henrik Pedersen (2024) A mass spectrometrical surface chemistry study of aluminum nitride ALD from tris-dimethylamido aluminum and ammonia Materials Advances (Article in journal) Continue to DOI
Sachin Sharma, Laurent Souqui, Justinas Palisaitis, Duc Quang Hoang, Ivan Gueorguiev Ivanov, Per O A Persson, Hans Högberg, Henrik Pedersen (2024) On the origin of epitaxial rhombohedral-B4C growth by CVD on 4H-SiC Dalton Transactions, Vol. 53, p. 10730-10736 (Article in journal) Continue to DOI
Pamburayi Mpofu, Houyem Hafdi, Pentti Niiranen, Jonas Lauridsen, Oscar Alm, Tommy Larsson, Henrik Pedersen (2024) Surface chemistry in atomic layer deposition of AlN thin films from Al(CH3)3 and NH3 studied by mass spectrometry Journal of Materials Chemistry C, Vol. 12, p. 12818-12824 (Article in journal) Continue to DOI
Collin Rowe, Ankit Kashyap, Geetu Sharma, Naveen Goyal, Johan G. Alauzun, Sean T. Barry, Narayanan Ravishankar, Ajay Soni, Per Eklund, Henrik Pedersen, Ganpati Ramanath (2024) Nanomolecularly-induced Effects at Titania/Organo-Diphosphonate Interfaces for Stable Hybrid Multilayers with Emergent Properties ACS Applied Nano Materials (Article in journal) Continue to DOI
Sachin Sharma, Justinas Palisaitis, Ivan Gueorguiev Ivanov, Per O A Persson, Henrik Pedersen, Hans Högberg (2024) The Influence of Carbon on Polytype and Growth Stability of Epitaxial Hexagonal Boron Nitride Films Advanced Materials Interfaces (Article in journal) Continue to DOI
Pentti Niiranen, Anna Kapran, Hama Nadhom, Martin Cada, Zdenek Hubicka, Henrik Pedersen, Daniel Lundin (2024) Plasma electron characterization in electron chemical vapor deposition Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, Vol. 42, Article 023006 (Article in journal) Continue to DOI

2023

Giane Damas, Karl Rönnby, Henrik Pedersen, Lars Ojamäe (2023) Thermal decomposition of trimethylindium and indium trisguanidinate precursors for InN growth: An ab initio and kinetic modeling study Journal of Chemical Physics, Vol. 158, Article 174313 (Article in journal) Continue to DOI
Karl Rönnby, Henrik Pedersen, Lars Ojamäe (2023) Surface chemical mechanisms of trimethyl aluminum in atomic layer deposition of AlN Journal of Materials Chemistry C, Vol. 11, p. 13935-13945 (Article in journal) Continue to DOI
Jing-Jia Huang, Christian Militzer, Charles Wijayawardhana, Urban Forsberg, Henrik Pedersen (2023) Superconformal silicon carbide coatings via precursor pulsed chemical vapor deposition Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, Vol. 41, Article 030403 (Article in journal) Continue to DOI
Karl Rönnby, Henrik Pedersen, Lars Ojamäe (2023) On the limitations of thermal atomic layer deposition of InN using ammonia Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, Vol. 41, Article 020401 (Article in journal) Continue to DOI
Arun Haridas Choolakkal, Hans Högberg, Jens Birch, Henrik Pedersen (2023) Conformal chemical vapor deposition of boron-rich boron carbide thin films from triethylboron Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, Vol. 41, Article 013401 (Article in journal) Continue to DOI
Pentti Niiranen, Hama Nadhom, Michal Zanaska, Robert Boyd, Mauricio Sortica, Daniel Primetzhofer, Daniel Lundin, Henrik Pedersen (2023) Biased quartz crystal microbalance method for studies of chemical vapor deposition surface chemistry induced by plasma electrons Review of Scientific Instruments, Vol. 94, Article 023902 (Article in journal) Continue to DOI
Henrik Pedersen, Hsu Chih-Wei, Neeraj Nepal, Jefferey M. Woodward, Charles R. Eddy (2023) Atomic Layer Deposition as the Enabler for the Metastable Semiconductor InN and Its Alloys Crystal Growth & Design, Vol. 23, p. 7010-7025 (Article in journal) Continue to DOI
M. Povoli, A. Kok, O. Koybasi, M. Getz, G. ONeill, D. Roehrich, E. Monakhov, Henrik Pedersen, Jens Birch, Arun Haridas Choolakkal, K. Kanaki, C. -C. Lai, R. Hall-Wilton, T. Slavicek, I. Llamas Jansa (2023) 3D silicon detectors for neutron imaging applications Journal of Instrumentation, Vol. 18, Article C01056 (Article in journal) Continue to DOI

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