Inspiration from nature
“We have been inspired by nature and its methods of sensing heat and radiation”, says Mina Shiran Chaharsoughi, doctoral student in the Organic Photonics and Nano-optics group at the Laboratory of Organic Electronics.Together with colleagues she has developed a sensor that combines pyroelectric and thermoelectric effects with a nano-optical phenomenon.
A voltage arises in pyroelectric materials when they are heated or cooled. It is the change in temperature that gives a signal, which is rapid and strong, but that decays almost as rapidly.
In thermoelectric materials, in contrast, a voltage arises when the material has one cold and one hot side. The signal here arises slowly, and some time must pass before it can be measured. The heat may arise from a warm touch or from the sun; all that is required is that one side is colder than the other.
“We wanted to enjoy the best of both worlds, so we combined a pyroelectric polymer with a thermoelectric gel developed in a previous project by Dan Zhao, Simone Fabiano and other colleagues at the Laboratory of Organic Electronics. The combination gives a rapid and strong signal that lasts as long as the stimulus is present”, says Magnus Jonsson, leader of the Organic Photonics and Nano-optics group.
Furthermore, it turned out that the two materials interact in a way that reinforces the signal.
Plasmons
The new sensor also uses another nano-optical entity known as plasmons.
“Plasmons arise when light interacts with nanoparticles of metals such as gold and silver. The incident light causes the electrons in the particles to oscillate in unison, which forms the plasmon. This phenomenon provides the nanostructures with extraordinary optical properties, such as high scattering and high absorption”, Magnus Jonsson explains.
In previous work, he and his co-workers have shown that a gold electrode that has been perforated with nanoholes absorbs light efficiently with the aid of plasmons. The absorbed light is subsequently converted to heat. With such an electrode, a thin gold film with nanoholes, on the side that faces the sun, the sensor can also convert visible light rapidly to a stable signal.
As an added bonus, the sensor is also pressure-sensitive.
“A signal arises when we press the sensor with a finger, but not when we subject it to the same pressure with a piece of plastic. It reacts to the heat of the hand”, says Magnus Jonsson.
In addition to Mina Shiran Chaharsoughi and Magnus Jonsson, their colleagues Dan Zhao, Simone Fabiano and Professor Xavier Crispin at the Laboratory of Organic Electronics have also contributed to the study, the results of which have recently been published in the scientific journal Advanced Functional Materials.
The research has been financed by, among other sources, the Swedish Foundation for Strategic Research, the Swedish Research Council, the Wenner-Gren Foundations, and the Strategic Initiative in Advanced Functional Materials, AFM, at Linköping University.
Translated by George Farrants
Thermodiffusion‐Assisted Pyroelectrics—Enabling Rapid and Stable Heat and Radiation Sensing, Mina Shiran Chaharsoughi, Dan Zhao, Xavier Crispin, Simone Fabiano, and Magnus P. Jonsson. Advanced Functional Materials, April 2019.
DOI 10.1002/adfm.201900572
